NANJING CHENGYOU RESINS CO., LTD.
Person:Miss Fu
Phone:025-57638338
Person:Miss Ye
Phone:025-57638818
Fax:025-57638778
Address:Double Lane Road 75, the new material industrial park Nanjing Chemical Industrial Park
Polyamide resin applied five factors in the field of separation and extraction
Polyamide resin applied five factors in the field of separation and extraction
Are: ( 1 ) the molecular weight flavonoids Shumu hydrogen bond forming groups related to the number , the greater the number of hydrogen bonds to form a group of the stronger adsorbed ;
( 2 ) formed on the position of hydrogen bonding groups , such as the location is easy to form intramolecular hydrogen bonds , the absorption capacity decreases.
(3 ) aromatic molecule higher degree , the more the conjugated double bond, then the stronger adsorption .
( 4 ) different types of flavonoids , are adsorbed strength of the order: flavonols > flavones > Dihydroflavonol > isoflavones.
( 5 ) and the solvent medium related. The ability to form hydrogen bonds in the water a strong , strong absorption in an organic solvent is less strong in an acidic solvent , alkaline solvent, the weakest , so the ability of various solvents in the polyamide column eluted from weak to strong the order is: water < methanol or ethanol ( concentration from low to high ) < acetone < dilute aqueous sodium hydroxide or ammonia < carboxamide < dimethylformamide < urea solution. Baiyun E series of studies [ 2] have been isolated total flavonoids Trollius polyamide , polyamide adsorption amount Comparison bell understanding of nasturtium and adsorption capacity of total flavonoids . The results showed that with 60 to 80 mesh polyamide solution for Lotus total flavonoid absorption and adsorption better.
[ 3 ] using the principle of polyamide adsorption of anthraquinone through hydrogen bonding , adsorption and separation as polyamide resin , polyamide first examined the adsorption capacity of Polygonum cuspidatum anthraquinone , adsorption kinetics and adsorption-desorption isotherms nature , from Jing is superior than the activated carbon adsorption absorption and desorption of silica gel as anthraquinone capacity and speed comparisons prove polyamide. Polyamide anthraquinone adsorption rate of 87.8% , the adsorption rate controlling step for the film diffusion control , ethanol eluent with more than 85% washout rate . Is a monolayer adsorption -based multilayer adsorption thermodynamics of adsorption behavior from anthraquinone on polyamide and came adsorption principle : monolayer adsorption contains chemical and physical adsorption , multilayer adsorption is mainly physical adsorption .